Decandrinin, an unprecedented \(C_9\)-spiro-fused 7,8-\( seco-ent\)-abietane from the Godavari mangrove \(Ceriops\ decandra\)

Please always quote using this URN: urn:nbn:de:bvb:20-opus-119983
  • Decandrinin (1), an unprecedented \(C_9\)-spiro-fused 7,8-\(seco-ent\)-abietane, was obtained from the bark of an Indian mangrove, \(Ceriops\ decandra\), collected in the estuary of Godavari, Andhra Pradesh. The constitution and the relative configuration of 1 were determined by HRMS (ESI) and extensive NMR investigations, and the absolute configuration by circular dichroism (CD) and optical-rotatory dispersion (ORD) spectroscopy in combination with quantum-chemical calculations. Decandrinin is the first 7,8-\(seco-ent\)-abietane.

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Author: Hui Wang, Min-Yi Li, Félix Zongwe Katele, Tirumani Satyanandamurty, Jun Wu, Gerhard Bringmann
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Organische Chemie
Parent Title (English):Beilstein Journal of Organic Chemistry
Year of Completion:2014
Source:Beilstein Journal of Organic Chemistry 2014, 10, 276–281. doi:10.3762/bjoc.10.23
Pubmed Id:
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 547 Organische Chemie
Tag:abietane; absolute configuration; ceriops decandra; circular dichroism; decandrinin; rhizophoraceae
Release Date:2015/11/18
Licence (German):License LogoCC BY: Creative-Commons-Lizenz: Namensnennung