Adducts of the parent boraphosphaketene H\(_2\)BPCO and their decarbonylative insertion chemistry

Please always quote using this URN: urn:nbn:de:bvb:20-opus-256470
  • The first examples of Lewis base adducts of the parent boraphosphaketene (H\(_2\)B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.

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Author: Stephan Hagspiel, Felipe Fantuzzi, Rian D. Dewhurst, Annalena Gärtner, Felix Lindl, Anna Lamprecht, Holger BraunschweigORCiD
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Parent Title (English):Angewandte Chemie International Edition
Year of Completion:2021
Source:Angewandte Chemie International Edition (2021) 60:24, 13666–13670. DOI: 10.1002/anie.202103521
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie
Tag:boron; decarbonylation; heterocycles; inorganic chemistry; ketenes; phosphorus
Release Date:2022/02/24
Licence (German):License LogoCC BY-NC: Creative-Commons-Lizenz: Namensnennung, Nicht kommerziell 4.0 International