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Erscheinungsjahr
- 2018 (1)
Dokumenttyp
- Dissertation (1)
Sprache
- Englisch (1) (entfernen)
Schlagworte
- Activation (1)
- BB bond activation (1)
- BB/BC Bond activation (1)
- BC bond activation (1)
- Bor (1)
- Boron (1)
- Catalysis (1)
- Copper (1)
- Copper catalysis (1)
- Kupfer katalyse (1)
Institut
- Institut für Anorganische Chemie (1) (entfernen)
The present thesis comprises synthesis and stoichiometric model reactions of well-defined NHC-stabilized copper(I) complexes (NHC = N-heterocyclic carbene) in order to understand their basic reactivity in borylation and cross-coupling reactions. This also includes the investigations of the reactivity of the ligands used (NHCs and CaaCs = cyclic alkyl(amino)carbenes) with the substrates, i.e. diboron(4) esters and arylboronates, which are addressed in the second part of the thesis.