@article{ArrowsmithBoehnkeBraunschweigetal.2016,
  author    = {Arrowsmith, Merle and B{\"o}hnke, Julian and Braunschweig, Holger and Celik, Mehmet and Dellermann, Theresa and Hammond, Kai},
  title     = {Uncatalyzed Hydrogenation of First-Row Main Group Multiple Bonds},
  series = {Chemistry, A European Journal},
  volume    = {22},
  journal   = {Chemistry, A European Journal},
  number    = {48},
  doi       = {10.1002/chem.201604094},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-139364},
  pages     = {17169 -- 17172},
  year      = {2016},
  abstract  = {Room temperature hydrogenation of an SIDep-stabilized diboryne (SIDep = 1,3-bis(diethylphenyl)-4,5-dihydroimidazol-2-ylidene) and a CAAC-supported diboracumulene (CAAC = 1-(2,6- diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) provided the first selective route to the corresponding 1,2-dihydrodiborenes. DFT calculations showed an overall exothermic (ΔG = 19.4 kcal mol\(^{-1}\) two-step asynchronous H\(_2\) addition mechanism proceeding via a bridging hydride.},
  subject      = {Diborane},
  language  = {en}
}
@article{MaierMarder2021,
  author    = {Maier, Jan and Marder, Todd B.},
  title     = {Mechanistic and Kinetic Factors of ortho-Benzyne Formation in Hexadehydro-Diels-Alder (HDDA) Reactions},
  series = {Chemistry - A European Journal},
  volume    = {27},
  journal   = {Chemistry - A European Journal},
  number    = {30},
  doi       = {10.1002/chem.202100608},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-239006},
  pages     = {7978 -- 7991},
  year      = {2021},
  abstract  = {With the rapid development of the hexadehydro-Diels-Alder reaction (HDDA) from its first discovery in 1997, the question of whether a concerted or stepwise mechanism better describes the thermally activated formation of ortho-benzyne from a diyne and a diynophile has been debated. Mechanistic and kinetic investigations were able to show that this is not a black or white situation, as minor changes can tip the balance. For that reason, especially, linked yne-diynes were studied to examine steric, electronic, and radical-stabilizing effects of their terminal substituents on the reaction mechanism and kinetics. Furthermore, the influence of the nature of the linker on the HDDA reaction was explored. The more recently discovered photochemical HDDA reaction also gives ortho-arynes, which display the same reactivity as the thermally generated ones, but their formation might not proceed by the same mechanism. This minireview summarizes the current state of mechanistic understanding of the HDDA reaction.},
  language  = {en}
}