@phdthesis{Rest2015,
  author    = {Rest, Christina},
  title     = {Self-assembly of amphiphilic oligo(phenylene ethynylene)-based (bi)pyridine ligands and their Pt(II) and Pd(II) complexes},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-133248},
  school      = {Universit{\"a}t W{\"u}rzburg},
  year      = {2015},
  abstract  = {The presented work in the field of supramolecular chemistry describes the synthesis and detailed investigation of (bi)pyridine-based oligo(phenylene ethynylene) (OPE) amphiphiles, decorated with terminal glycol chains. The metal-ligating property of these molecules could be exploited to coordinate to Pd(II) and Pt(II) metal ions, respectively, resulting in the creation of novel metallosupramolecular π-amphiphiles of square-planar geometry. The focus of the presented studies is on the self-assembly behaviour of the OPE ligands and their corresponding metal complexes in polar and aqueous environment. In this way, the underlying aggregation mechanism (isodesmic or cooperative) is revealed and the influence of various factors on the self-assembly process in supramolecular systems is elucidated. In this regard, the effect of the molecular design of the ligand, the coordination to a metal centre as well as the surrounding medium, the pH value and temperature is investigated.},
  subject      = {Supramolekulare Chemie},
  language  = {en}
}
@phdthesis{Rehm2015,
  author    = {Rehm, Stefanie},
  title     = {Spermine-functionalized Perylene Bisimide Dyes: Synthesis and Self-assembly in Water},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-123201},
  school      = {Universit{\"a}t W{\"u}rzburg},
  year      = {2015},
  abstract  = {The main objective of this thesis was the design and synthesis of perylene bisimide dyes with sufficient water-solubility for the construction of self-assembled architectures in aqueous solutions. Beside these tasks another goal of this project was the control over the self-assembly process in terms of aggregate size and helicity, respectively. Within this thesis an appropriate synthesis for spermine-functionalized perylene bisimide dyes was developed and conducted successfully. The characterization of these building blocks and their course of self-assembly were investigated by NMR, UV/Vis and fluorescence spectroscopy as well as by atomic force and transmission electron microscopy. For the better understanding of the experimental results theoretical calculations were performed.},
  subject      = {Perylenderivate},
  language  = {en}
}