@article{RiadZlotosHolzgrabe2015,
  author    = {Riad, Noura M. and Zlotos, Darius P. and Holzgrabe, Ulrike},
  title     = {Crystal structure of 5,11-dihydropyrido[2,3-b][1,4]benzodiazepin-6-one.},
  series = {Acta Crystallographica Section E Crystallographic Communications},
  volume    = {E71},
  journal   = {Acta Crystallographica Section E Crystallographic Communications},
  doi       = {10.1107/S2056989015006817},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-149627},
  pages     = {o304-o305},
  year      = {2015},
  abstract  = {The title compound, C\(_{12}\)H\(_{9}\)N\(_{3}\)O, is an inter­mediate in the synthesis of the muscarinic M2 receptor antagonist AFDX-384. The seven-membered ring adopts a boat conformation and the dihedral angle between the planes of the aromatic rings is 41.51 (9)°. In the crystal, mol­ecules are linked into [001] chains of alternating inversion dimers formed by pairs of N-H・・・O hydrogen bonds and pairs of N-H・・・N hydrogen bonds. In both cases, R\(_{2}\)\(^{2}\)(8) loops are generated.},
  language  = {en}
}
@article{ArnoldBraunschweigDamme2012,
  author    = {Arnold, Nicole and Braunschweig, Holger and Damme, Alexander},
  title     = {Bis(μ-diisopropyl-phosphanido-\(κ^2\)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)]},
  series = {Acta crystallographica. Section E, Structure reports online},
  volume    = {E68},
  journal   = {Acta crystallographica. Section E, Structure reports online},
  doi       = {http://dx.doi.org/10.1107/S1600536812022829},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-123723},
  pages     = {m808},
  year      = {2012},
  abstract  = {In the centrosymmetric molecular structure of the title compound \([Pt_2(C_6H_{14}P)_2H_2)(C_9H_{21}P)_2]\), each \(Pt^{II}\) atom is bound on one side to a phosphane ligand \((PiPr_3)\) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands \((μ-PiPr_2)\), which engage a bridging position between the two \(Pt^{II}\) atoms, forming a distorted square-planar structure motif. The PtPt distance is 3.6755(2){\AA}. A comparable molecular structure was observed for bis-(μ-di-tert-butyl-phosphanido)bis-[hydrido(triethyl-phosphane)platinum(II)] [Itazaki et al. (2004 ). Organometallics, 23, 1610-1621].},
  language  = {en}
}
@article{Gessner2012,
  author    = {Gessner, Viktoria H.},
  title     = {Diphenyl[2-(phenyl-sulfon-yl)propan-2-yl]-\(\lambda^5\)-phosphanethione},
  series = {Acta crystallographica. Section E, Structure reports online},
  volume    = {E68},
  journal   = {Acta crystallographica. Section E, Structure reports online},
  number    = {o1045},
  doi       = {10.1107/S1600536812010082},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-123635},
  year      = {2012},
  abstract  = {The title compound, \(C_{21}H_{21}O_2PS_2\), was obtained from the corresponding dilithio methandiide by treatment with iodo-methane. The bond lengths and angles deviate considerably from those in the dimetallated compound. These differences are most pronounced in the PCS backbone. While the title compound features C-P and C-S distances of 1.9082(17) and 1.8348(17){\AA}, respectively, the dianion showed \(C-P_{av}\) distances shortened by 11\% [1.710(4){\AA}] and C-S distances shortened by 12\% [1.614(3){\AA}]. Additionally, the P-C-S angle experiences a contraction by methyl-ation of the dianion from 121.4(2) to 111.96(9)° in the title compound.},
  language  = {en}
}
@article{Gessner2014,
  author    = {Gessner, Viktoria H.},
  title     = {Diphenyl[(phenylsulfanyl)methyl]-\(λ^5\)-phosphanethione},
  series = {Acta Crystallographica, Section E: Structure Reports},
  volume    = {70},
  journal   = {Acta Crystallographica, Section E: Structure Reports},
  number    = {3},
  doi       = {10.1107/S1600536814004292},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-120174},
  pages     = {o374},
  year      = {2014},
  abstract  = {The title compound, \(C_{19}H_{17}PS_2\), results from the direct deprotonation of di­phenyl­methyl­phosphine sulfide and subsequent reaction with diphenyl di­sulfide. The C-P and C-S bond lengths of 1.8242 (18) and 1.8009 (18) {\AA}, respectively, of the central P-C-S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the di­phenyl­methyl moiety is 69.46 (7)°. No distinct inter­molecular inter­actions are present in the crystal structure.},
  language  = {en}
}
@article{BraunschweigKramer2014,
  author    = {Braunschweig, Holger and Kramer, T.},
  title     = {Crystal structure of μ-1κC:2(\(η^2\))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2\(κ^2\) B:B-[1(\(η^5\))-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate},
  volume    = {70},
  number    = {11},
  doi       = {10.1107/S1600536814023381},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-120120},
  pages     = {421-423},
  year      = {2014},
  abstract  = {In the mol­ecular structure of the dinuclear title compound \([η^5-(C_5(CH_3)_5)(CO)Fe{(μ-BCl)(μ-CO)}PtCl(P(C_6H_{11})_3)]·C_6H_6\), the two metal atoms, iron(II) and platinum(II), are bridged by one carbonyl (μ-CO) and one chlorido­borylene ligand (μ-BCl). The \(Pt^{II}\) atom is additionally bound to a chloride ligand situated trans to the bridging borylene, and a tri­cyclo­hexyl­phosphane ligand \((PCy_3)\) trans to the carbonyl ligand, forming a distorted square-planar structural motif at the \(Pt^{II}\) atom. The \(Fe_{II}\) atom is bound to a penta­methyl­cyclo­penta­dienyl ligand \([η^5-C_5(CH_3)_5]\) and one carbonyl ligand (CO), forming a piano-stool structure. Additionally, one benzene solvent mol­ecule is incorporated into the crystal structure, positioned staggered relative to the penta­methyl­cyclo­penta­dienyl ligand at the \(Fe^{II}\) atom, with a centroid-centroid separation of 3.630 (2) {\AA}.},
  language  = {en}
}
@article{ArnoldBraunschweigGruss2011,
  author    = {Arnold, Thomas and Braunschweig, Holger and Gruss, Katrin},
  title     = {cyclo-Tri-mu-oxido-tris{[(eta 5,eta 5)-1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene},
  series = {Acta Crystallographica Section E: metal-organic compounds},
  volume    = {67},
  journal   = {Acta Crystallographica Section E: metal-organic compounds},
  doi       = {10.1107/S1600536811007094},
  url       = {http://nbn-resolving.de/urn:nbn:de:bvb:20-opus-134802},
  pages     = {M391-sup-23},
  year      = {2011},
  abstract  = {The title compound, [Zr(3)(C(14)H(20)Si(2))(3)O(3)], consists of three disila-bridged zirconocene units, which are connected via an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) A. The compound was isolated as a by-product from a mixture of [(C(5)H(4)SiMe(2))(2)ZrCl(2)] and Li[AlH(4)] in Et(2)O.},
  language  = {en}
}