Refine
Has Fulltext
- yes (7)
Is part of the Bibliography
- yes (7)
Document Type
- Journal article (5)
- Doctoral Thesis (1)
- Preprint (1)
Language
- English (7)
Keywords
- heterocycles (7) (remove)
Institute
EU-Project number / Contract (GA) number
- 669054 (1)
Adducts of the parent boraphosphaketene H\(_2\)BPCO and their decarbonylative insertion chemistry
(2021)
The first examples of Lewis base adducts of the parent boraphosphaketene (H\(_2\)B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.