Filtern
Volltext vorhanden
- ja (4)
Gehört zur Bibliographie
- ja (4) (entfernen)
Erscheinungsjahr
- 2017 (4)
Dokumenttyp
Sprache
- Englisch (4)
Schlagworte
- boron (3)
- Boron (1)
- C-H activation (1)
- CH activation (1)
- Diboranes (1)
- Tetrafluorodiborane (1)
- bond activation (1)
- borylation (1)
- diboraindanes (1)
- diborane (1)
- diboranes (1)
- diborene (1)
- silylenes (1)
- synthetic methods (1)
- transition metal complex (1)
- transition metals (1)
Institut
Sonstige beteiligte Institutionen
EU-Projektnummer / Contract (GA) number
- 669054 (4) (entfernen)
Simple Solution-Phase Syntheses of Tetrahalodiboranes(4) and their Labile Dimethylsulfide Adducts
(2017)
Convenient, solution-phase syntheses of tetrahalodiboranes(4) B\(_2\)F\(_4\), B\(_2\)Cl\(_4\) and B\(_2\)I\(_4\) are presented herein from common precursor B\(_2\)Br\(_4\). In addition, the dimethylsulfide adducts B\(_2\)Cl\(_4\)(SMe\(_2\))\(_2\) and B\(_2\)Br\(_4\)(SMe\(_2\))\(_2\) are conveniently prepared in one-step syntheses from the commercially-available starting material B\(_2\)(NMe\(_2\))\(_4\). The results provide simple access to the full range of tetrahalodiboranes(4) for the exploration of their untapped synthetic potential.