Refine
Has Fulltext
- yes (8)
Is part of the Bibliography
- yes (8)
Document Type
- Journal article (7)
- Preprint (1)
Language
- English (8)
Keywords
- 2Dimensionale Spektroskopie (2)
- EEA (2)
- Exziton (2)
- Spektroskopie (2)
- boron (2)
- exciton-exciton (2)
- 1,4-naphthoquinone (1)
- Acene (1)
- Bindungsaktivierung (1)
- Biradikale (1)
Institute
Sonstige beteiligte Institutionen
EU-Project number / Contract (GA) number
- 614623 (2)
We calculate two-dimensional (2D) spectra reflecting the time-dependent electronic predissociation of a diatomic molecule. The laser-excited electronic state is coupled non-adiabatically to a fragment channel, leading to the decay of the prepared quasi-bound states. This decay can be monitored by the three-pulse configuration employed in optical 2D spectroscopy. It is shown that in this way it is possible to state-selectively characterize the time-dependent population of resonance states with different lifetimes. A model of the NaI molecule serves as a numerical example.