Refine
Has Fulltext
- yes (4)
Is part of the Bibliography
- yes (4)
Document Type
- Journal article (3)
- Preprint (1)
Language
- English (4) (remove)
Keywords
- boron (3)
- inorganic chemistry (2)
- Beryllium (1)
- CH activation (1)
- EDA-NOCV (1)
- X-ray crystallography (1)
- bond activation (1)
- boryl anion (1)
- borylation (1)
- cumulene (1)
- cyclic alkyl(amino)carbene (1)
- decarbonylation (1)
- diboraindanes (1)
- diborane (1)
- diboranes (1)
- heterocycles (1)
- ketenes (1)
- nucleophile (1)
- phosphorus (1)
- radical (1)
- silylenes (1)
- synthetic methods (1)
Institute
EU-Project number / Contract (GA) number
- 669054 (1)
Cyclic alkyl(amino)carbene-stabilized (cyano)hydroboryl anions were synthesized by deprotonation of (cyano)dihydroborane precursors. While they display boron-centered nucleophilic reactivity towards organohalides, generating fully unsymmetrically substituted cyano(hydro)organoboranes, they show cyano-nitrogen-centered nucleophilic reactivity towards haloboranes, resulting in the formation of hitherto unknown linear 2-aza-1,4-diborabutatrienes.