Refine
Has Fulltext
- yes (3)
Is part of the Bibliography
- yes (3)
Document Type
- Journal article (2)
- Doctoral Thesis (1)
Keywords
- Beryllium (2)
- Beryllafluorene (1)
- Beryllole (1)
- Dibenzoberyllole (1)
- EDA-NOCV (1)
- Heterocyclische Verbindungen (1)
- X-ray crystallography (1)
- antiaromaticity (1)
- aromaticity (1)
- beryllium (1)
- cyclic alkyl(amino)carbene (1)
- heterocycles (1)
- inorganic chemistry (1)
- radical (1)
- s-block metals (1)
The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, UV/Vis spectroscopy and X-ray crystallography. DFT calculations show significant spin density at beryllium and confirm donor–acceptor bonding between an alkylberyllium radical fragment and a neutral CAAC ligand.