Refine
Has Fulltext
- yes (18)
Is part of the Bibliography
- yes (18)
Document Type
- Journal article (15)
- Preprint (3)
Language
- English (18) (remove)
Keywords
- photoelectron spectroscopy (3)
- radicals (3)
- synchrotron radiation (3)
- IR spectroscopy (2)
- TEM (2)
- antimicrobial activities (2)
- exciton dynamics (2)
- nano rods (2)
- photolysis (2)
- pyrene dimer (2)
- pyrolysis (2)
- reactive intermediates (2)
- silver (2)
- time-resolved photoelectron spectroscopy (2)
- Bor (1)
- Boron (1)
- Excited state dynamics (1)
- Heterocycles (1)
- Heterocyclische Verbindungen (1)
- Hydrocarbon radicals (1)
- Jahn–Teller effect (1)
- Multiple bonds (1)
- Nonadiabatic dynamics (1)
- PAH formation (1)
- Photoelektronenspektroskopie (1)
- Raman-scattering (1)
- Selen (1)
- Selenium (1)
- Tellur (1)
- Tellurium (1)
- ammonia borane (1)
- benzyl radical (1)
- biradicals (1)
- carbon monoxide (1)
- chemistry (1)
- dissociative photoionisation (1)
- excimer formation (1)
- field-induced surface hopping (1)
- free electron laser (1)
- free jet (1)
- gas phase (1)
- gold nanoparticles (1)
- high-temperature chemistry (1)
- hydrogen storage (1)
- ionization energy (1)
- ionization potential (1)
- methylbismuth (1)
- molecular orbitals (1)
- nanostructures (1)
- nanowire formation (1)
- nitrogen trichloride (1)
- organic electronics (1)
- p-block element (1)
- particles (1)
- radical reactions (1)
- synchrotron radiatoren (1)
- tetracene dimer (1)
- threshold photoelectron spectroscopy (1)
- xylylene (1)
Institute
Sonstige beteiligte Institutionen
Isolated 2‐phenylallyl radicals (2‐PA), generated by pyrolysis from a nitrite precursor, have been investigated by IR/UV ion dip spectroscopy using free electron laser radiation. 2‐PA is a resonance‐stabilized radical that is considered to be involved in the formation of polycyclic aromatic hydrocarbons (PAH) in combustion, but also in interstellar space. The radical is identified based on its gas‐phase IR spectrum. Furthermore, a number of bimolecular reaction products are identified, showing that the self‐reaction as well as reactions with unimolecular decomposition products of 2‐PA form several PAH efficiently. Possible mechanisms are discussed and the chemistry of 2‐PA is compared with the one of the related 2‐methylallyl and phenylpropargyl radicals.