Refine
Has Fulltext
- yes (5)
Is part of the Bibliography
- yes (5)
Document Type
- Journal article (2)
- Preprint (2)
- Doctoral Thesis (1)
Keywords
- boron (2)
- diborenes (2)
- Borylanion (1)
- Borylene (1)
- Diboren (1)
- Diborene (1)
- N-heterocyclic carbenes (1)
- boron-bound hydrogen (1)
- boryl anion (1)
- borylenes (1)
Institute
- Institut für Anorganische Chemie (5) (remove)
EU-Project number / Contract (GA) number
- 669054 (2)
Cyclic alkyl(amino)carbene-stabilized (cyano)hydroboryl anions were synthesized by deprotonation of (cyano)dihydroborane precursors. While they display boron-centered nucleophilic reactivity towards organohalides, generating fully unsymmetrically substituted cyano(hydro)organoboranes, they show cyano-nitrogen-centered nucleophilic reactivity towards haloboranes, resulting in the formation of hitherto unknown linear 2-aza-1,4-diborabutatrienes.