Refine
Has Fulltext
- yes (22)
Is part of the Bibliography
- yes (22)
Document Type
- Preprint (16)
- Journal article (6)
Keywords
- boron (10)
- diborenes (7)
- carbenes (6)
- Boron (4)
- diborene (3)
- Aromaticity (2)
- Biradicals (2)
- Cycloaddition (2)
- Diborane (2)
- Multiple bonds (2)
Institute
Sonstige beteiligte Institutionen
EU-Project number / Contract (GA) number
- 669054 (22) (remove)
The reaction of aryl‐ and amino(dihydro)boranes with dibora[2]ferrocenophane 1 leads to the formation 1,3‐trans ‐dihydrotriboranes by formal hydrogenation and insertion of a borylene unit into the B=B bond. The aryltriborane derivatives undergo reversible photoisomerization to the cis ‐1,2‐μ‐H‐3‐hydrotriboranes, while hydride abstraction affords cationic triboranes, which represent the first doubly base‐stabilized B3H4\(^+\) analogues.