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Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds (2019)
Muessig, Jonas H. ; Thaler, Melanie ; Dewhurst, Rian D. ; Paprocki, Valerie ; Seufert, Jens ; Mattock, James D. ; Vargas, Alfredo ; Braunschweig, Holger
The lability of B=B, B-P and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.
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