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Conjugated Bis(triarylboranes) with Disconnected Conjugation (2021)
Riensch, Nicolas Alexander ; Swoboda, Lukas ; Lik, Artur ; Krummenacher, Ivo ; Braunschweig, Holger ; Helten, Holger
A series of methylene-bridged bis(triarylboranes) has been synthesized via two complementary routes using metal-free catalytic Si/B exchange condensation under mild conditions. The title compounds comprise two borane moieties that show effective internal π-conjugation involving the respective boron centers and the adjacent hetaryl groups. Conjugation between both borane units, however, is disrupted by the aliphatic linker. Cyclic voltammetry revealed minimal electronic communication between the boron centers, as evidenced by two closely spaced reduction processes. The UV-vis spectra showed bathochromic shifted absorption bands compared to related monoboranes, which is attributed to the methylene bridge. A further red-shift results upon introduction of methyl or SiMe\(_3\) groups at the terminal thiophene rings.
Controlled Synthesis of Oligomers Containing Main-Chain B(sp\(^{2}\))-B(sp\(^{2}\)) Bonds (2021)
Schorr, Fabian ; Schopper, Nils ; Riensch, Nicolas ; Fantuzzi, Felipe ; Neder, Marco ; Dewhurst, Rian D. ; Thiess, Thorsten ; Brückner, Tobias ; Hammond, Kai ; Helten, Holger ; Finze, Maik ; Braunschweig, Holger
A number of novel alkynyl-functionalized diarylbis(dimethylamino)diboranes(4) are prepared by salt metathesis, and the appended alkynyl groups are subjected to hydroboration. Their reactions with monohydroboranes lead to discrete boryl-appended diborane(4) species, while dihydroboranes induce their catenation to oligomeric species, the first known examples of well-characterized macromolecular species with B−B bonds. The oligomeric species were found to comprise up to ten repeat units and are soluble in common organic solvents. Some of the oligomeric species have good air stability and all were characterized by NMR and vibrational spectroscopy and size-exclusion chromatography techniques.
Dithiophene‐Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics (2021)
Crumbach, Merian ; Bachmann, Jonas ; Fritze, Lars ; Helbig, Andreas ; Krummenacher, Ivo ; Braunschweig, Holger ; Helten, Holger
Access to dithiophene‐fused oxadiborepins and the first azadiborepins attained via a modular synthesis route are presented. The new compounds emit intense blue light, some of which demonstrate fluorescence quantum yields close to unity. Cyclic voltammetry (CV) revealed electrochemically reversible one‐electron reduction processes. The weak aromatic character of the novel 1,2,7‐azadiborepin ring is demonstrated with in‐depth theoretical investigations using nucleus‐independent chemical shift (NICS) scans and anisotropy of the induced current density (ACID) calculations.
Phenylpyridyl-fused boroles: a unique coordination mode and weak B-N coordination-induced dual fluorescence (2021)
He, Jiang ; Rauch, Florian ; Friedrich, Alexandra ; Krebs, Johannes ; Krummenacher, Ivo ; Bertermann, Rüdiger ; Nitsch, Jörn ; Braunschweig, Holger ; Finze, Maik ; Marder, Todd B.
Phenylpyridyl-fused boroles [TipPBB1]\(_4\) and TipPBB2 were synthesized and their properties investigated. [TipPBB1]\(_4\) forms a tetramer in both the solid state and solution. TipPBB2 contains a 4-coordinate boron atom in the solid state but dissociates to give a 3-coordinate boron species in solution. TipPBB2 shows interesting temperature-dependent dual fluorescence in solution because of the equilibrium between 3- and 4-coordinate boron species due to weak N⋅⋅⋅B intermolecular coordination.
Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates (2021)
Hagspiel, Stephan ; Arrowsmith, Merle ; Fantuzzi, Felipe ; Vargas, Alfredo ; Rempel, Anna ; Hermann, Alexander ; Brückner, Tobias ; Braunschweig, Holger
Reduction of (CAAC)BBr\(_2\)(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.
Probing the Boundaries between Lewis-Basic and Redox Behavior of a Parent Borylene (2021)
Arrowsmith, Merle ; Endres, Sara ; Heinz, Myron ; Nestler, Vincent ; Holthausen, Max C. ; Braunschweig, Holger
The parent borylene (CAAC)(Me\(_{3}\)P)BH, 1 (CAAC=cyclic alkyl(amino)carbene), acts both as a Lewis base and one-electron reducing agent towards group 13 trichlorides (ECl\(_{3}\), E=B, Al, Ga, In), yielding the adducts 1-ECl\(_{3}\) and increasing proportions of the radical cation [1]\(^{•+}\) for the heavier group 13 analogues. With boron trihalides (BX\(_{3}\), X=F, Cl, Br, I) 1 undergoes sequential adduct formation and halide abstraction reactions to yield borylboronium cations and shows an increasing tendency towards redox processes for the heavier halides. Calculations confirm that 1 acts as a strong Lewis base towards EX3 and show a marked increase in the B−E bond dissociation energies down both group 13 and the halide group.
Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes (2020)
Schmidt, Uwe ; Fantuzzi, Felipe ; Arrowsmith, Merle ; Hermann, Alexander ; Prieschl, Dominic ; Rempel, Anna ; Engels, Bernd ; Braunschweig, Holger
Whereas the reduction of N-heterocyclic carbene (NHC)-stabilised cymantrenyldibromoboranes, (NHC)BBr\(_2\)Cym, in benzene results in formation of the corresponding diborenes (NHC)\(_2\)B\(_2\)Cym\(_2\), a change of solvent to THF yields a borylene of the form (NHC)\(_2\)BCym, stabilised through its boratafulvene resonance form.
Reduktion und Umlagerung eines Bor(I)‐Carbonylkomplexes (2021)
Rang, Maximilian ; Fantuzzi, Felipe ; Arrowsmith, Merle ; Krummenacher, Ivo ; Beck, Eva ; Witte, Robert ; Matler, Alexander ; Rempel, Anna ; Bischof, Tobias ; Radacki, Krzysztof ; Engels, Bernd ; Braunschweig, Holger
Bei der Einelektronenreduktion eines durch eine cyclisches (Alkyl)(amino)carben (CAAC) stabilisierten Arylborylen-Carbonylkomplexes erfolgt die Bildung eines dimeren Borylketyl-Radikalanions, bedingt durch eine intramolekulare Arylmigration zum CO Kohlenstoffatom. Computergestützte Analyse liefert Hinweise auf eine radikalanionische [(CAAC)B(CO)Ar]\(^{.-}\) Zwischenstufe. Weiterführende Reduktion des entstandenen Komplexes liefert ein hoch nukleophiles (Boranyliden)methanolat.
Isolation and Reactivity of an Antiaromatic s‐Block Metal Compound (2021)
Roy, Dipak Kumar ; Tröster, Tobias ; Fantuzzi, Felipe ; Dewhurst, Rian D. ; Lenczyk, Carsten ; Radacki, Krzysztof ; Pranckevicius, Conor ; Engels, Bernd ; Braunschweig, Holger
The concepts of aromaticity and antiaromaticity have a long history, and countless demonstrations of these phenomena have been made with molecules based on elements from the p, d, and f blocks of the periodic table. In contrast, the limited oxidation‐state flexibility of the s‐block metals has long stood in the way of their participation in sophisticated π‐bonding arrangements, and truly antiaromatic systems containing s‐block metals are altogether absent or remain poorly defined. Using spectroscopic, structural, and computational techniques, we present herein the synthesis and authentication of a heterocyclic compound containing the alkaline earth metal beryllium that exhibits significant antiaromaticity, and detail its chemical reduction and Lewis‐base‐coordination chemistry.
{N ',N ''-Bis[2,6-bis(1-methylethyl)phenyl]-N,N-dimethylguanidinato-kappa N-2 ',N ''}dibromidoborane (2010)
Braunschweig, Holger ; Dewhurst, Rian D. ; Schwab, Katrin ; Wagner, Katharina
In the molecular structure of the title compound, C27H40N3BBr2, the B atom is connected to two bromide substituents and a guanidinate scaffold, forming a four– membered ring. An aryl group is connected to each N atom in the ring that contains two isopropyl groups in positions 2 and 6.
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