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  • nitrogen trichloride (1)
  • photoelectron spectroscopy (1)
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  • Braunschweig, Holger (1)
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Photoelectron Photoion Coincidence Spectroscopy of NCl\(_{3}\) and NCl\(_{2}\) (2021)
Gerlach, Marius ; Monninger, Sophie ; Schleier, Domenik ; Hemberger, Patrick ; Goettel, James T. ; Braunschweig, Holger ; Fischer, Ingo
We investigate NCl\(_{3}\) and the NCl\(_{2}\) radical by photoelectron-photoion coincidence spectroscopy using synchrotron radiation. The mass selected threshold photoelectron spectrum (ms-TPES) of NCl\(_{3}\) is broad and unstructured due to the large geometry change. An ionization energy of 9.7±0.1 eV is estimated from the spectrum and supported by computations. NCl2 is generated by photolysis at 213 nm from NCl\(_{3}\) and its ms-TPES shows an extended vibrational progression with a 90 meV spacing that is assigned to the symmetric N−Cl stretching mode in the cation. An adiabatic ionization energy of 9.94 ± 0.02 eV is determined.
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