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Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates (2021)
Hagspiel, Stephan ; Arrowsmith, Merle ; Fantuzzi, Felipe ; Vargas, Alfredo ; Rempel, Anna ; Hermann, Alexander ; Brückner, Tobias ; Braunschweig, Holger
Reduction of (CAAC)BBr\(_2\)(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.
Hydrophosphination of boron–boron multiple bonds (2020)
Stennett, Tom E. ; Jayaraman, Arumugam ; Brückner, Tobias ; Schneider, Lea ; Braunschweig, Holger
Five compounds containing boron–boron multiple bonds are shown to undergo hydrophosphination reactions with diphenylphosphine in the absence of a catalyst. With diborenes, the products obtained are highly dependent on the substitution pattern at the boron atoms, with both 1,1- and 1,2- hydrophosphinations observed. With a symmetrical diboryne, 1,2-hydrophosphination yields a hydro(phosphino)diborene. The different mechanistic pathways for the hydrophosphination of diborenes are rationalised with the aid of density functional theory calculations.
Mild synthesis of diboryldiborenes by diboration of B–B triple bonds (2019)
Brückner, Tobias ; Dewhurst, Rian D. ; Dellermann, Theresa ; Müller, Marcel ; Braunschweig, Holger
A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B–B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents.
Rethinking Borole Cycloaddition Reactivity (2021)
Lindl, Felix ; Guo, Xueying ; Krummenacher, Ivo ; Rauch, Florian ; Rempel, Anna ; Paprocki, Valerie ; Dellermann, Theresa ; Stennett, Tom E. ; Lamprecht, Anna ; Brückner, Tobias ; Radacki, Krzysztof ; Bélanger-Chabot, Guillaume ; Marder, Todd B. ; Lin, Zhenyang ; Braunschweig, Holger
Boroles are attracting broad interest for their myriad and diverse applications, including in synthesis, small molecule activation and functional materials. Their properties and reactivity are closely linked to the cyclic conjugated diene system, which has been shown to participate in cycloaddition reactions, such as the Diels-Alder reaction with alkynes. The reaction steps leading to boranorbornadienes, borepins and tricyclic boracyclohexenes from the thermal reaction of boroles with alkynes are seemingly well understood as judged from the literature. Herein, we question the long-established mechanistic picture of pericyclic rearrangements by demonstrating that seven-membered borepins (i. e., heptaphenylborepin and two derivatives substituted with a thienyl and chloride substituent on boron) exist in a dynamic equilibrium with the corresponding bicyclic boranorbornadienes, the direct Diels-Alder products, but are not isolable products from the reactions. Heating gradually converts the isomeric mixtures into fluorescent tricyclic boracyclohexenes, the most stable isomers in the series. Results from mechanistic DFT calculations reveal that the tricyclic compounds derive from the boranorbornadienes and not the borepins, which were previously believed to be intermediates in purely pericyclic processes.
Controlled Synthesis of Oligomers Containing Main-Chain B(sp\(^{2}\))-B(sp\(^{2}\)) Bonds (2021)
Schorr, Fabian ; Schopper, Nils ; Riensch, Nicolas ; Fantuzzi, Felipe ; Neder, Marco ; Dewhurst, Rian D. ; Thiess, Thorsten ; Brückner, Tobias ; Hammond, Kai ; Helten, Holger ; Finze, Maik ; Braunschweig, Holger
A number of novel alkynyl-functionalized diarylbis(dimethylamino)diboranes(4) are prepared by salt metathesis, and the appended alkynyl groups are subjected to hydroboration. Their reactions with monohydroboranes lead to discrete boryl-appended diborane(4) species, while dihydroboranes induce their catenation to oligomeric species, the first known examples of well-characterized macromolecular species with B−B bonds. The oligomeric species were found to comprise up to ten repeat units and are soluble in common organic solvents. Some of the oligomeric species have good air stability and all were characterized by NMR and vibrational spectroscopy and size-exclusion chromatography techniques.
Isolation of neutral, mono-, and dicationic B\(_2\)P\(_2\) rings by diphosphorus addition to a boron-boron triple bond (2021)
Brückner, Tobias ; Fantuzzi, Felipe ; Stennett, Tom E. ; Krummenacher, Ivo ; Dewhurst, Rian D. ; Engels, Bernd ; Braunschweig, Holger
The NHC-stabilised diboryne (B\(_2\)(SIDep)\(_2\); SIDep=1,3-bis(2,6-diethylphenyl)imidazolin-2-ylidene) undergoes a high-yielding P−P bond activation with tetraethyldiphosphine at room temperature to form a B\(_2\)P\(_2\) heterocycle via a diphosphoryldiborene by 1,2-diphosphination. The heterocycle can be oxidised to a radical cation and a dication, respectively, depending on the oxidant used and its counterion. Starting from the planar, neutral 1,3-bis(alkylidene)-1,3-diborata-2,4-diphosphoniocyclobutane, each oxidation step leads to decreased B−B distances and loss of planarity by cationisation. X-ray analyses in conjunction with DFT and CASSCF/NEVPT2 calculations reveal closed-shell singlet, butterfly-shaped structures for the NHC-stabilised dicationic B\(_2\)P\(_2\) rings, with their diradicaloid, planar-ring isomers lying close in energy.
Single and double activation of acetone by isolobal B≡N and B≡B triple bonds (2018)
Böhnke, Julian ; Brückner, Tobias ; Hermann, Alexander ; González-Belman, Oscar F. ; Arrowsmith, Merle ; Jiménez-Halla, J. Oscar C. ; Braunschweig, Holger
B≡N and B≡B triple bonds induce C-H activation of acetone to yield a (2-propenyloxy)aminoborane and an unsymmetrical 1-(2- propenyloxy)-2-hydrodiborene, respectively. DFT calculations showed that, despite their stark electronic differences, both the B≡N and B≡B triple bonds activate acetone via a similar coordination-deprotonation mechansim. In contrast, the reaction of acetone with a cAAC-supported diboracumulene yielded a unique 1,2,3-oxadiborole, which according to DFT calculations also proceeds via an unsymmetrical diborene, followed by intramolecular hydride migration and a second C-H activation of the enolate ligand.
Reaction of Dihalodiboranes(4) with N-Heterocyclic Silylenes: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes (2017)
Braunschweig, Holger ; Brückner, Tobias ; Deißenberger, Andrea ; Dewhurst, Rian ; Gackstatter, Annika ; Gärtner, Annalena ; Hofmann, Alexander ; Kupfer, Thomas ; Prieschl, Dominic ; Thiess, Torsten ; Wang, Sunewang Rixin
Dihalodiboranes(4) react with an N-heterocyclic silylene (NHSi) to generate NHSi-adducts of 1-aryl-2-silyl-1,2-diboraindanes as confirmed by X-ray crystallography, featuring the functionalization of both B–X (X = halogen) bonds and a C–H bond under mild conditions. Coordination of a third NHSi to the proposed 1,1-diaryl- 2,2-disilyldiborane(4) intermediates, generated by a two-fold B–X insertion, may be crucial for the C–H borylation that leads to the final products. Notably, our results demonstrate the first C–H borylation with a strong B–F bond activated by silylene insertion.
Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne (2019)
Brückner, Tobias ; Arrowsmith, Merle ; Heß, Merlin ; Hammond, Kai ; Müller, Marcel ; Braunschweig, Holger
The addition of alkynes to a staturated N-heterocyclic carbene (NHC)-supported diboryne results in spontaneous cycloaddition, with complete B≡B and C≡C triple bond cleavage, NHC ring- expansion and activation of a variety of C-H bonds, leading to the formation of complex mixtures of fused B,N-heterocycles.
Single and Double Hydroboration of B-B Triple Bonds and Conver- gent Routes to a Cationic Tetraborane (2019)
Brückner, Tobias ; Stennett, Tom E. ; Heß, Merlin ; Braunschweig, Holger
A compound with a boron-boron triple bond is shown to undergo stepwise hydroboration reactions with catecholborane to yield an unsymmetrical hydro(boryl)diborene and a 2,3-dihydrotetraborane. Abstraction of H– from the latter compound produces an unusual cationic, planar tetraborane with a hydrogen atom bridging the central B2 moiety. Spectroscopic and crystallographic data and DFT calculations support a ‘protonated diborene’ structure for this compound, which can also be accessed via direct protonation of the corresponding diborene.
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