Refine
Has Fulltext
- yes (10)
Is part of the Bibliography
- yes (10)
Document Type
- Journal article (6)
- Preprint (3)
- Doctoral Thesis (1)
Keywords
- Diborene (2)
- diborenes (2)
- Aspergillus fumigatus (1)
- Bor (1)
- Boranes (1)
- Boron (1)
- Borylene (1)
- Cymantren (1)
- DEL(5Q) (1)
- DFT mechanism (1)
Institute
EU-Project number / Contract (GA) number
- 669054 (5)
The reaction of aryl‐ and amino(dihydro)boranes with dibora[2]ferrocenophane 1 leads to the formation 1,3‐trans ‐dihydrotriboranes by formal hydrogenation and insertion of a borylene unit into the B=B bond. The aryltriborane derivatives undergo reversible photoisomerization to the cis ‐1,2‐μ‐H‐3‐hydrotriboranes, while hydride abstraction affords cationic triboranes, which represent the first doubly base‐stabilized B3H4\(^+\) analogues.