Diphenyl[(phenylsulfanyl)methyl]-\(λ^5\)-phosphanethione
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- The title compound, \(C_{19}H_{17}PS_2\), results from the direct deprotonation of diphenylmethylphosphine sulfide and subsequent reaction with diphenyl disulfide. The C-P and C-S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P-C-S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the diphenylmethyl moiety is 69.46 (7)°. No distinct intermolecular interactionsThe title compound, \(C_{19}H_{17}PS_2\), results from the direct deprotonation of diphenylmethylphosphine sulfide and subsequent reaction with diphenyl disulfide. The C-P and C-S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P-C-S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the diphenylmethyl moiety is 69.46 (7)°. No distinct intermolecular interactions are present in the crystal structure.…
Autor(en): | Viktoria H. Gessner |
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URN: | urn:nbn:de:bvb:20-opus-120174 |
Dokumentart: | Artikel / Aufsatz in einer Zeitschrift |
Institute der Universität: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Sprache der Veröffentlichung: | Englisch |
Titel des übergeordneten Werkes / der Zeitschrift (Englisch): | Acta Crystallographica, Section E: Structure Reports |
Erscheinungsjahr: | 2014 |
Band / Jahrgang: | 70 |
Heft / Ausgabe: | 3 |
Seitenangabe: | o374 |
Originalveröffentlichung / Quelle: | Acta Crystallographica (2014). E70, o374. doi:10.1107/S1600536814004292 |
DOI: | https://doi.org/10.1107/S1600536814004292 |
Allgemeine fachliche Zuordnung (DDC-Klassifikation): | 5 Naturwissenschaften und Mathematik / 54 Chemie / 548 Kristallografie |
Freie Schlagwort(e): | crystal structure |
Datum der Freischaltung: | 01.12.2015 |
Lizenz (Deutsch): | CC BY: Creative-Commons-Lizenz: Namensnennung |