Copper‐Catalyzed Oxidative Cross‐Coupling of Electron‐Deficient Polyfluorophenylboronate Esters with Terminal Alkynes
Please always quote using this URN: urn:nbn:de:bvb:20-opus-224362
- We report herein a mild procedure for the copper‐catalyzed oxidative cross‐coupling of electron‐deficient polyfluorophenylboronate esters with terminal alkynes. This method displays good functional group tolerance and broad substrate scope, generating cross‐coupled alkynyl(fluoro)arene products in moderate to excellent yields. Thus, it represents a simple alternative to the conventional Sonogashira reaction.
Author: | Zhiqiang Liu, Yudha P. Budiman, Ya‐Ming Tian, Alexandra Friedrich, Mingming Huang, Stephen A. Westcott, Udo Radius, Todd B. Marder |
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URN: | urn:nbn:de:bvb:20-opus-224362 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Chemistry – A European Journal |
Year of Completion: | 2020 |
Volume: | 26 |
Issue: | 71 |
First Page: | 17267 |
Last Page: | 17274 |
Source: | Chemistry – A European Journal 2020, 26(71):17267-17274. DOI: 10.1002/chem.202002888 |
DOI: | https://doi.org/10.1002/chem.202002888 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Tag: | Sonogashira reaction; boronate esters; coupling reactions; fluorine; fluoroarenes |
Release Date: | 2021/12/15 |
Licence (German): | CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |