Ionic liquids-assisted ring opening of three-membered heterocycles with thio- and seleno-silanes
Please always quote using this URN: urn:nbn:de:bvb:20-opus-290350
- Ring opening reactions of strained heterocycles (epoxides, aziridines, thiiranes) by silyl chalcogenides, such as thiosilanes and selenosilanes, can be efficiently performed in a variety of ionic liquids, which can behave as reaction media and in some cases also as catalysts. This protocol enables an alternative access to β-functionalized sulfides and selenides under mild conditions.
| Author: | Damiano Tanini, Tommaso Pecchi, Nikolai V. Ignat’ev, Antonella Capperucci |
|---|---|
| URN: | urn:nbn:de:bvb:20-opus-290350 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Catalysts |
| ISSN: | 2073-4344 |
| Year of Completion: | 2022 |
| Volume: | 12 |
| Issue: | 10 |
| Article Number: | 1259 |
| Source: | Catalysts (2022) 12:10, 1259. https://doi.org/10.3390/catal12101259 |
| DOI: | https://doi.org/10.3390/catal12101259 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Tag: | ionic liquids; ring opening reactions; selenolysis; silyl selenides; silyl sulfides; thiolysis |
| Release Date: | 2023/11/07 |
| Date of first Publication: | 2022/10/17 |
| Licence (German): |  CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |