Diphenyl[(phenylsulfanyl)methyl]-\(λ^5\)-phosphanethione
Please always quote using this URN: urn:nbn:de:bvb:20-opus-120174
- The title compound, \(C_{19}H_{17}PS_2\), results from the direct deprotonation of diphenylmethylphosphine sulfide and subsequent reaction with diphenyl disulfide. The C-P and C-S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P-C-S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the diphenylmethyl moiety is 69.46 (7)°. No distinct intermolecular interactionsThe title compound, \(C_{19}H_{17}PS_2\), results from the direct deprotonation of diphenylmethylphosphine sulfide and subsequent reaction with diphenyl disulfide. The C-P and C-S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P-C-S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the diphenylmethyl moiety is 69.46 (7)°. No distinct intermolecular interactions are present in the crystal structure.…
Author: | Viktoria H. Gessner |
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URN: | urn:nbn:de:bvb:20-opus-120174 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | English |
Parent Title (English): | Acta Crystallographica, Section E: Structure Reports |
Year of Completion: | 2014 |
Volume: | 70 |
Issue: | 3 |
Pagenumber: | o374 |
Source: | Acta Crystallographica (2014). E70, o374. doi:10.1107/S1600536814004292 |
DOI: | https://doi.org/10.1107/S1600536814004292 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 548 Kristallografie |
Tag: | crystal structure |
Release Date: | 2015/12/01 |
Licence (German): | CC BY: Creative-Commons-Lizenz: Namensnennung |