Eine pentagonal pyramidale Koordination des Bismuts. Kristallstruktur von Methylbismutbis(dietyldithiocarbonat)
A pentagonal pyramidal coordination of Bismut. Crystal structure of Methylbismuthbis(diethyldithiocar bamate)
Please always quote using this URN: urn:nbn:de:bvb:20-opus-46750
- The crystal structure of the title compound, recrystallized from ethanol, was solved by means of X-ray diffraction methods and could be refined to an R-value of 0.050 with 2126 reflections observed. In contrast to its behaviour in benzene solution, where the compound is monomerie, in the crystalline state dimerie units are formed by intermoleeular Bi-S-interactions. The bismuth atoms are coordinated in form of a slightly distorted pentagonal pyramid with the free electron pair presumably directed opposite the apical C-atom.
Author: | Christian Burschka, Markus Wieber |
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URN: | urn:nbn:de:bvb:20-opus-46750 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Language: | German |
Year of Completion: | 1979 |
Source: | In: Zeitschrift fuer Naturforschung Teil B: Anorganische Chemie, Organische Chemie (1979) 34B, 7, S. 1037 - 1039. |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
GND Keyword: | Chemie |
Release Date: | 2010/11/23 |
Licence (German): | Deutsches Urheberrecht |