CO\(_2\) Binding and Splitting by Boron–Boron Multiple Bonds

Please always quote using this URN: urn:nbn:de:bvb:20-opus-164265
  • CO\(_2\) is found to undergo room-temperature, ambient- pressure reactions with two species containing boron-boron multiple bonds, leading to incorporation of either one or two CO\(_2\) molecules. In one case, a thermally-unstable intermediate was structurally characterized, indicating the operation of an initial 2+2 cycloaddition mechanism in the reaction.

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Author: Andreas Stoy, Julian Böhnke, J. Oscar C. Jiménez-Halla, Rian D. Dewhurst, Torsten Thiess, Holger BraunschweigORCiD
Document Type:Preprint
Faculties:Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie
Parent Title (English):Angewandte Chemie, International Edition
Year of Completion:2018
Source:Angewandte Chemie International Edition 2018, 57,5947–5951. DOI:10.1002/anie.201802117
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 546 Anorganische Chemie
Tag:CO2 fixation; boron; carbon dioxide; diborenes; diborynes
Release Date:2018/07/24
EU-Project number / Contract (GA) number:669054
This is the pre-peer reviewed version of the following article: A. Stoy, J. Böhnke, J. O. C. Jiménez‐Halla, R. D. Dewhurst, T. Thiess, H. Braunschweig, Angew. Chem. Int.Ed. 2018, 57,5947 –5951, which has been published in final form at DOI: 10.1002/anie.201802117. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Licence (German):License LogoDeutsches Urheberrecht