cyclo-Tri-mu-oxido-tris{[(eta 5,eta 5)-1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
Please always quote using this URN: urn:nbn:de:bvb:20-opus-134802
- The title compound, [Zr(3)(C(14)H(20)Si(2))(3)O(3)], consists of three disila-bridged zirconocene units, which are connected via an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) A. The compound was isolated as a by-product from a mixture of [(C(5)H(4)SiMe(2))(2)ZrCl(2)] and Li[AlH(4)] in Et(2)O.
| Author: | Thomas Arnold, Holger BraunschweigORCiD, Katrin Gruss |
|---|---|
| URN: | urn:nbn:de:bvb:20-opus-134802 |
| Document Type: | Journal article |
| Faculties: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
| Language: | English |
| Parent Title (English): | Acta Crystallographica Section E: metal-organic compounds |
| Year of Completion: | 2011 |
| Volume: | 67 |
| Pagenumber: | M391-sup-23 |
| Source: | Acta Cryst. (2011). E67, m391-sup-23 |
| DOI: | https://doi.org/10.1107/S1600536811007094 |
| Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 548 Kristallografie |
| Tag: | Kristallographie |
| Release Date: | 2019/03/25 |
| Licence (German): |  CC BY: Creative-Commons-Lizenz: Namensnennung |