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  • 1974 (2)
  • 1973 (1)

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  • Organische Chemie (1)

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  • Brüntrup, Gisela (3) (remove)

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  • Institut für Organische Chemie (3)

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Diimine Reduction and Ozonolysis of Benzvalene (1974)
Christl, Manfred ; Brüntrup, Gisela
Via reduction of benzvalene (1) with diirnine tricyclo[3.1.0.02•6]hexane is obtained in good yield. The procedure renders 3, which has already been synthesized by Lemal and Shim, accessible much easier and in larger quantities. IH and 13C n.m.r. spectroscopic data are discussed. Both the thermal and the AgBF4-catalyzed rearrangernent of 3 yield 1,3-cyclohexadiene (8). - The ozonolysis of 1 with subsequent LiAIH4-reduction results in cis-I,3- bis(hydroxyrnethyl)cyclobutane (13a).
Neue Isomere des Cycloheptatriens: Tricyclo[4.1.0.0^(2,7)]hept-3-en und Tetracyclo[4.1.0.0^(2,4).0^(3,5)]heptan (1974)
Christl, Manfred ; Brüntrup, Gisela
No abstract available
Darstellung und Thermolyse der Hexamethyldewarbenzol-Cycloaddukte aromatischer Nitriloxide und des Diphenylnitrilimins (1973)
Brüntrup, Gisela ; Christl, Manfred
No abstract available
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