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We report the discovery of a charge transfer (CT) related low binding energy feature at a molecule-metal interface by the application of resonant photoelectron spectroscopy (RPES). This interface feature is neither present for molecular bulk samples nor for the clean substrate. A detailed analysis of the spectroscopic signature of the low binding energy feature shows characteristics of electronic interaction not found in other electron spectroscopic techniques. Within a cluster model description this feature is assigned to a particular eigenstate of the photoionized system that is invisible in direct photoelectron spectroscopy but revealed in RPES through a relative resonant enhancement. Interpretations based on considering only the predominant character of the eigenstates explain the low binding energy feature by an occupied lowest unoccupied molecular orbital, which is either realized through CT in the ground or in the intermediate state. This reveals that molecule-metal CT is responsible for this feature. Consequently, our study demonstrates the sensitivity of RPES to electronic interactions and constitutes a new way to investigate CT at molecule-metal interfaces.
We have observed thermal gating, i.e. electrostatic gating induced by hot electrons. The effect occurs in a device consisting of two capacitively coupled quantum dots. The double dot system is coupled to a hot electron reservoir on one side (QD1), while the conductance of the second dot (QD2) is monitored. When a bias across QD2 is applied we observe a current which is strongly dependent on the temperature of the heat reservoir. This current can be either enhanced or suppressed, depending on the relative energetic alignment of the QD levels. Thus, the system can be used to control a charge current by hot electrons.
The 2010 eruption of Eyjafjallajokull volcano was characterized by pulsating activity. Discrete ash bursts merged at higher altitude and formed a sustained quasi-continuous eruption column. High-resolution near-field videos were recorded on 8-10 May, during the second explosive phase of the eruption, and supplemented by contemporary aerial observations. In the observed period, pulses occurred at intervals of 0.8 to 23.4 s (average, 4.2 s). On the basis of video analysis, the pulse volume and the velocity of the reversely buoyant jets that initiated each pulse were determined. The expansion history of jets was tracked until the pulses reached the height of transition from a negatively buoyant jet to a convective buoyant plume about 100 m above the vent. Based on the assumption that the density of the gas-solid mixture making up the pulse approximates that of the surrounding air at the level of transition from the jet to the plume, a mass flux ranging between 2.2 and 3.5 . 10\(^4\) kg/s was calculated. This mass eruption rate is in good agreement with results obtained with simple models relating plume height with mass discharge at the vent. Our findings indicate that near-field measurements of eruption source parameters in a pulsating eruption may prove to be an effective monitoring tool. A comparison of the observed pulses with those generated in calibrated large-scale experiments reveals very similar characteristics and suggests that the analysis of near-field sensors could in the future help to constrain the triggering mechanism of explosive eruptions.
An Overview of the Regional Experiments for Land-atmosphere Exchanges 2012 (REFLEX 2012) Campaign
(2015)
The REFLEX 2012 campaign was initiated as part of a training course on the organization of an airborne campaign to support advancement of the understanding of land-atmosphere interaction processes. This article describes the campaign, its objectives and observations, remote as well as in situ. The observations took place at the experimental Las Tiesas farm in an agricultural area in the south of Spain. During the period of ten days, measurements were made to capture the main processes controlling the local and regional land-atmosphere exchanges. Apart from multi-temporal, multi-directional and multi-spatial space-borne and airborne observations, measurements of the local meteorology, energy fluxes, soil temperature profiles, soil moisture profiles, surface temperature, canopy structure as well as leaf-level measurements were carried out. Additional thermo-dynamical monitoring took place at selected sites. After presenting the different types of measurements, some examples are given to illustrate the potential of the observations made.