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- 2014 (1) (entfernen)
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- Englisch (1)
Schlagworte
- abietane (1)
- absolute configuration (1)
- ceriops decandra (1)
- circular dichroism (1)
- decandrinin (1)
- rhizophoraceae (1)
Institut
Decandrinin (1), an unprecedented \(C_9\)-spiro-fused 7,8-\(seco-ent\)-abietane, was obtained from the bark of an Indian mangrove, \(Ceriops\ decandra\), collected in the estuary of Godavari, Andhra Pradesh. The constitution and the relative configuration of 1 were determined by HRMS (ESI) and extensive NMR investigations, and the absolute configuration by circular dichroism (CD) and optical-rotatory dispersion (ORD) spectroscopy in combination with quantum-chemical calculations. Decandrinin is the first 7,8-\(seco-ent\)-abietane.