Refine
Has Fulltext
- yes (1)
Is part of the Bibliography
- yes (1)
Year of publication
- 2019 (1)
Document Type
- Preprint (1)
Language
- English (1)
Keywords
- DFT mechanism (1)
- amine borane dehydrocoupling (1)
- diboranes (1)
- diborene (1)
- transfer hydrogenation (1)
Institute
EU-Project number / Contract (GA) number
- 669054 (1)
The transfer hydrogenation of NHC-supported diborenes with dimethylamine borane proceeds with high selectivity for the trans-1,2-dihydrodiboranes(6). DFT calculations suggest a stepwise proton-first-hydride-second reaction mechanism via an intermediate μ-hydrodiboronium dimethylaminoborate ion pair.