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Supramolecular frameworks based on [60]fullerene hexakisadducts
Zitieren Sie bitte immer diese URN: urn:nbn:de:bvb:20-opus-171996
- [60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and[60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and sorption measurements.…
Autor(en): | Andreas Kraft, Johannes Stangl, Ana-Maria Krause, Klaus Müller-Buschbaum, Florian Beuerle |
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URN: | urn:nbn:de:bvb:20-opus-171996 |
Dokumentart: | Artikel / Aufsatz in einer Zeitschrift |
Institute der Universität: | Fakultät für Chemie und Pharmazie / Institut für Anorganische Chemie |
Fakultät für Chemie und Pharmazie / Institut für Organische Chemie | |
Sprache der Veröffentlichung: | Englisch |
Titel des übergeordneten Werkes / der Zeitschrift (Englisch): | Beilstein Journal of Organic Chemistry |
Erscheinungsjahr: | 2017 |
Band / Jahrgang: | 13 |
Seitenangabe: | 1-9 |
Originalveröffentlichung / Quelle: | Beilstein Journal of Organic Chemistry (2017) 13, 1-9. https://doi.org/10.3762/bjoc.13.1 |
DOI: | https://doi.org/10.3762/bjoc.13.1 |
PubMed-ID: | https://pubmed.ncbi.nlm.nih.gov/28179942 |
Allgemeine fachliche Zuordnung (DDC-Klassifikation): | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
Freie Schlagwort(e): | chemistry; fullerenes; hexakisadducts; hydrogen bonding; porous materials; structure elucidation |
Datum der Freischaltung: | 11.02.2021 |
Lizenz (Deutsch): | CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |