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Direct observation of ultrafast coherent exciton dynamics in helical π-stacks of self-assembled perylene bisimides
Zitieren Sie bitte immer diese URN: urn:nbn:de:bvb:20-opus-148157
- Ever since the discovery of dye self-assemblies in nature, there have been tremendous efforts to exploit biomimetic supramolecular assemblies for tailored artificial photon processing materials. This feature necessarily has resulted in an increasing demand for understanding exciton dynamics in the dye self-assemblies. In a sharp contrast with pi-type aggregates, however, the detailed observation of exciton dynamics in H-type aggregates has remained challenging. In this study, as we succeed in measuring transient fluorescence from Frenkel stateEver since the discovery of dye self-assemblies in nature, there have been tremendous efforts to exploit biomimetic supramolecular assemblies for tailored artificial photon processing materials. This feature necessarily has resulted in an increasing demand for understanding exciton dynamics in the dye self-assemblies. In a sharp contrast with pi-type aggregates, however, the detailed observation of exciton dynamics in H-type aggregates has remained challenging. In this study, as we succeed in measuring transient fluorescence from Frenkel state of π-stacked perylene tetracarboxylic acid bisimide dimer and oligomer aggregates, we present an experimental demonstration on Frenkel exciton dynamics of archetypal columnar π-π stacks of dyes. The analysis of the vibronic peak ratio of the transient fluorescence spectra reveals that unlike the simple π-stacked dimer, the photoexcitation energy in the columnar π-stacked oligomer aggregates is initially delocalized over at least three molecular units and moves coherently along the chain in tens of femtoseconds, preceding excimer formation process.…
Autor(en): | Jooyoung Sung, Pyosang Kim, Benjamin Fimmel, Frank WürthnerORCiDGND, Dongho Kim |
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URN: | urn:nbn:de:bvb:20-opus-148157 |
Dokumentart: | Artikel / Aufsatz in einer Zeitschrift |
Institute der Universität: | Fakultät für Chemie und Pharmazie / Institut für Organische Chemie |
Sprache der Veröffentlichung: | Englisch |
Titel des übergeordneten Werkes / der Zeitschrift (Englisch): | Nature Communications |
Erscheinungsjahr: | 2015 |
Band / Jahrgang: | 6 |
Heft / Ausgabe: | 8646 |
Originalveröffentlichung / Quelle: | Nature Communications 6:8646 (2015). DOI: 10.1038/ncomms9646 |
DOI: | https://doi.org/10.1038/ncomms9646 |
Allgemeine fachliche Zuordnung (DDC-Klassifikation): | 5 Naturwissenschaften und Mathematik / 54 Chemie / 547 Organische Chemie |
Freie Schlagwort(e): | J-aggregate behavior; absorption; diffusion; excimer formation; fluorescence; molecules; organic semiconductors; photoluminescence; spectroscopy; systems |
Datum der Freischaltung: | 06.11.2018 |
Lizenz (Deutsch): | CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |