Microtubular Self-Assembly of Covalent Organic Frameworks
Please always quote using this URN: urn:nbn:de:bvb:20-opus-227373
- Despite significant progress in the synthesis of covalent organic frameworks (COFs), reports on the precise construction of template-free nano- and microstructures of such materials have been rare. In the quest for dye-containing porous materials, a novel conjugated framework DPP-TAPP-COF with an enhanced absorption capability up to λ=800 nm has been synthesized by utilizing reversible imine condensations between 5,10,15,20-tetrakis(4-aminophenyl)porphyrin (TAPP) and a diketopyrrolopyrrole (DPP) dialdehyde derivative. Surprisingly, the obtainedDespite significant progress in the synthesis of covalent organic frameworks (COFs), reports on the precise construction of template-free nano- and microstructures of such materials have been rare. In the quest for dye-containing porous materials, a novel conjugated framework DPP-TAPP-COF with an enhanced absorption capability up to λ=800 nm has been synthesized by utilizing reversible imine condensations between 5,10,15,20-tetrakis(4-aminophenyl)porphyrin (TAPP) and a diketopyrrolopyrrole (DPP) dialdehyde derivative. Surprisingly, the obtained COF exhibited spontaneous aggregation into hollow microtubular assemblies with outer and inner tube diameters of around 300 and 90 nm, respectively. A detailed mechanistic investigation revealed the time-dependent transformation of initial sheet-like agglomerates into the tubular microstructures.…
Author: | Bappaditya Gole, Vladimir Stepanenko, Sabrina Rager, Matthias Grüne, Dana D. Medina, Thomas Bein, Frank Würthner, Florian Beuerle |
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URN: | urn:nbn:de:bvb:20-opus-227373 |
Document Type: | Journal article |
Faculties: | Fakultät für Chemie und Pharmazie / Institut für Organische Chemie |
Language: | English |
Parent Title (English): | Angewandte Chemie International Edition |
Year of Completion: | 2018 |
Volume: | 57 |
Pagenumber: | 846-850 |
Source: | Angewandte Chemie International Edition (2018) 57:846-850. https://doi.org/10.1002/anie.201708526 |
DOI: | https://doi.org/10.1002/anie.201708526 |
Dewey Decimal Classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 547 Organische Chemie |
Tag: | covalent organic frameworks; diketopyrrolopyrroles; imines; microtubes; porphyrins |
Release Date: | 2024/08/21 |
EU-Project number / Contract (GA) number: | 321339 |
OpenAIRE: | OpenAIRE |
Licence (German): | CC BY: Creative-Commons-Lizenz: Namensnennung 4.0 International |