Rearrangement of Free Radicals, XII. ESR Spectroscopic Study of the Ring Opening of the Homobenzvalenyl Radical

Please always quote using this URN: urn:nbn:de:bvb:20-opus-58376
  • Abstraction of an allylic hydrogen atom in homobenzvalene (4) either in solurion by photolyticaßy generated tert-butoxyl radicals or in an adamantane matrix by X-rays produces the homobcnzvalenyl radical (5). which tbennally rearranps · to tbe tropylium ndical (1). In solution tbe activation cnergy for the rate determined step of the reaction sequence was detennined· to be 13.4 ± O.S kcal/mol.

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Author: H.-G. Korth, W. Müller, R. Sustmann, Manfred Christl
Document Type:Journal article
Faculties:Fakultät für Chemie und Pharmazie / Institut für Organische Chemie
Year of Completion:1987
Source:In: Chemische Berichte (1987) 120, 1257-1258.
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
GND Keyword:Organische Chemie
Release Date:2011/09/01
Licence (German):License LogoDeutsches Urheberrecht